Called “the snail” by the Italians, and “the monkey” by the Dutch, the @ symbol was first documented in use in 1536.
Our elegant @ has been inducted into the permanent collection of the Museum of Modern Art.
In 1971, Ray Tomlinson was working at BBN Networks (where he still works) on developing a communication system (between programmers so they could be connected across their computers) for Arpanet, a precursor to the Internet. He needed a key on his Model 33 teletype keyboard which was not already in use by the programmers. And the @ sign was brought forward from its obscurity.
Here’s a gem from the Smithsonian Magazine online:
http://www.smithsonianmag.com/science-nature/The-Accidental-History-of-the-at-Symbol-165593146.html
And here is a post from Ray Tomlinson himself on this first use of the @ symbol:
openmap.bbn.com/~tomlinso/ray/firstemailframe.html
I must say I am delighted to find these stories, and grateful.